Oxygenates by Homologation or CO Hydrogenation with Metal Complexes

Oxygenates by Homologation or CO Hydrogenation with Metal Complexes edited by A. Braca.

Born and initially developed in various industrial laboratories, mainly in U.S.A. and Gennany, homogeneous phase catalytic carbon monoxide hydrogenation and alcohols and their derivatives carbonylation and homologation, have generally been considered and reviewed separately in the course of their 40...

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Bibliographic Details
Corporate Author: SpringerLink (Online service)
Other Authors: Braca, A. (Editor)
Format: eBook
Language:English
Published: Dordrecht : Springer Netherlands : Imprint: Springer, 1994.
Edition:1st ed. 1994.
Series:Catalysis by Metal Complexes, 16
Springer eBook Collection.
Subjects:
Organometallic chemistry .
Catalysis.
Physical chemistry.
Inorganic chemistry.
Organic chemistry.
Chemical engineering.
Electronic resources (E-books)
Online Access:Click to view e-book
Holy Cross Note:Loaded electronically.
Electronic access restricted to members of the Holy Cross Community.
Table of Contents:
  • Monoalcohols, Glycols, and their Ethers and Esters by CO Hydrogenation
  • Department of Chemistry and Industrial Chemistry, University of Pisa, ITALY
  • 1 Introduction
  • 2 Cobalt catalysts
  • 3 Ruthenium Catalysts
  • 4 Rhodium catalysts
  • 5 Other catalysts
  • 6 Reaction mechanism
  • 7 Industrial process development
  • 8 References
  • Alcohols and Derivatives by Homologation with Syn Gas
  • Department of Chemistry and Industrial Chemistry, University of Pisa (ITALY)
  • 1 Introduction
  • 2 Hydrocarbonylation of alcohols
  • 3 Hydrocarbonylation of aliphatic ethers
  • 4 Hydrocarbonylation of carboxylic acid esters
  • 5 Homologation of acetic acid in the presence of ruthenium/iodide or rhodium/iodide catalysts
  • 6 Homologation of methyl halides
  • 7 Reactiom mechanism
  • 8 Industrial processes development
  • 9 References
  • Hydrocarbonylation of aldehydes and their derivatives
  • SNAM PROGETTI S.p.A. S.Donato Milanese (ITALY)
  • 1 Introduction
  • 2 Hydroformylation of formaldehyde to glycol aldehyde
  • 3 Hydrocarbonylation of formaldehyde to ethylene glycol
  • 4 Hydrocarbonylation of formaldehyde to acetaldehyde and/or ethanol
  • 5 Hydrocarbonylation of formaldehyde to higher oxygenated products
  • 6 Hydrocarbonylation of higher aldehydes
  • 7 Conclusions
  • 8 References.

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