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Semiclassical Methods in Molec...
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Semiclassical Methods in Molecular Scattering and Spectroscopy Proceedings of the NATO ASI held in Cambridge, England, in September 1979 / edited by M.S. Child.
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Bibliographic Details
Corporate Author:
SpringerLink (Online service)
Other Authors:
Child, M.S
(Editor)
Format:
eBook
Language:
English
Published:
Dordrecht :
Springer Netherlands : Imprint: Springer,
1980.
Edition:
1st ed. 1980.
Series:
Nato Science Series C:, Mathematical and Physical Sciences,
53
Springer eBook Collection.
Subjects:
Analytical chemistry.
Spectroscopy.
Electronic resources (E-books)
Online Access:
Click to view e-book
Holy Cross Note:
Loaded electronically.
Electronic access restricted to members of the Holy Cross Community.
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Table of Contents
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Table of Contents:
Semiclassical and Higher Order Approximations: Properties. Solution of Connection Problems
1. Introduction
2. First order JWKB approximation
3. Method for solving connection problems
4. Anti-Stokes’ and Stokes’ Lines
5. Properties of the JWKB Approximation in the complex plane
6. Bohr-Sommerfeld quantization condition
7. Phase shift
8. Normalization
9. Expectation values and matrix elements
10. Higher order approximations
11. Exercises
References
Semiclassical Theory of Elastic Scattering
1. Introduction
2. Quantum mechanical elastic scattering
3. Classical elastic scattering
4. The semiclassical phase shift
5. Semiclassical evaluation of f(?)
6. Orbiting collisions and resonances
7. Regge pole representation of f(?)
References
Problems
Applications of Bohr Quantization in Diatomic Molecule Spectroscopy
1. Introduction
2. Spectroscopic properties of the potential function
3. RKR inversion
4. Near dissociation behaviour of diatomic molecules
5. Problems
References
Separable Spectroscopy Applications
1. Frack-Condon factors and predissociation
2. Tunneling and curve-crossing problems
3. Problems
References
The Classical S Matrix
1. Classical considerations
2. Derivations of the S matrix
3. Problems
References
Semiclassical Theory of Eletronically Non-Adiabatic Transitions in Molecular Collisions Processes
1. Introductory concepts and tools
2. Specific theories and dynamical models
3. Miller-George theory of electronic transitions
4. Applications of the semiclassical S matrix
5. Interaction with fields. Laser-enhanced collisions
6. Miscellaneous aspects of laser-enhanced collisions
Problems
References
Correspondence-Principle Methods for Molecular Collisions
1. Introduction
2. Bound states and matrix elements
3. Cross sections
4. Collinear vibrational excitation
5. Rotational excitation
6. Rotational-vibrational excitation and rotor-rotor collisions
7. Conclusions
Problems
References
The Determination of Bound States by Semiclassical Methods
1. The nature of classical trajectories
2. Methods for determining semiclassical eigenvalues
3. Quantum effects of classical ergodicity
References
Appendix. M. S. Child/The Airy Function
1. Properties
References
Author Index.
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