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|a 9783540444749
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|a 10.1007/3-540-44474-2
|2 doi
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|a Transition Metal and Rare Earth Compounds
|h [electronic resource] :
|b Excited States, Transitions, Interactions II /
|c edited by Hartmut Yersin.
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| 250 |
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|a 1st ed. 2001.
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| 264 |
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|a Berlin, Heidelberg :
|b Springer Berlin Heidelberg :
|b Imprint: Springer,
|c 2001.
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| 300 |
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|a X, 186 p.
|b online resource.
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|a text
|b txt
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|a text file
|b PDF
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| 490 |
1 |
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|a Topics in Current Chemistry,
|x 0340-1022 ;
|v 214
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| 490 |
1 |
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|a Springer eBook Collection
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|a Upconversion Processes in Transition Metal and Rare Earth Metal Systems -- Geometric and Electronic Information from the Spectroscopy of Six-Coordinate Copper(II) Compounds -- Low-Lying Electronic States and Photophysical Properties of Organometallic Pd(II) and Pt(II) Compounds. Modern Research Trends Presented in Detailed Case Studies.
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| 520 |
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|a There exists a large literature on the spectroscopic properties of copper(II) com- 9 pounds. This is due to the simplicity of the d electron configuration, the wide variety of stereochemistries that copper(II) compounds can adopt, and the f- xional geometric behavior that they sometimes exhibit [1]. The electronic and geometric properties of a molecule are inexorably linked and this is especially true with six-coordinate copper(II) compounds which are subject to a Jahn-T- ler effect.However,the spectral-structural correlations that are sometimes d- wn must often be viewed with caution as the information contained in a typical solution UV-Vis absorption spectrum of a copper(II) compound is limited. Meaningful spectral-structural correlations can be obtained in a related series of compounds where detailed spectroscopic data is available. In the fol- 4– lowing sections two such series are examined; the six-coordinate CuF and 6 2+ Cu(H O) ions doped as impurities in single crystal hosts.Using low tempera- 2 6 ture polarized optical spectroscopy and electron paramagnetic resonance, a very detailed picture can be drawn about the geometry of these ions in both their ground and excited electronic states. We then compare the spectrosco- cally determined structural data with that obtained from X-ray diffraction or EXAFS measurements.
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|a Loaded electronically.
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|a Electronic access restricted to members of the Holy Cross Community.
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| 650 |
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|a Organic chemistry.
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| 650 |
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|a Physical chemistry.
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| 650 |
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|a Inorganic chemistry.
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| 650 |
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|a Lasers.
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| 650 |
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|a Photonics.
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| 690 |
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|a Electronic resources (E-books)
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| 700 |
1 |
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|a Yersin, Hartmut.
|e editor.
|4 edt
|4 http://id.loc.gov/vocabulary/relators/edt
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| 710 |
2 |
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|a SpringerLink (Online service)
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| 773 |
0 |
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|t Springer eBooks
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| 830 |
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|a Topics in Current Chemistry,
|x 0340-1022 ;
|v 214
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| 830 |
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|a Springer eBook Collection.
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| 856 |
4 |
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|u https://holycross.idm.oclc.org/login?auth=cas&url=https://doi.org/10.1007/3-540-44474-2
|3 Click to view e-book
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