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|a 10.1007/978-3-642-58252-3
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|a Flexible Polymer Chains in Elongational Flow
|h [electronic resource] :
|b Theory and Experiment /
|c edited by Tuan Q. Nguyen, Hans-Henning Kausch.
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| 250 |
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|a 1st ed. 1999.
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| 264 |
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|a Berlin, Heidelberg :
|b Springer Berlin Heidelberg :
|b Imprint: Springer,
|c 1999.
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| 300 |
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|a XVII, 401 p.
|b online resource.
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|a text
|b txt
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|a Springer eBook Collection
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|a 1 Tortured Chains: An Introduction -- 2 Polymer Solutions in Flow: A Non-Equilibrium Molecular Dynamics Approach -- 2.1 Introduction -- 2.2 Molecular Dynamics of Dilute Solutions of Chains in Homogeneous Flow -- 2.3 The Equilibrium Case -- 2.4 Polymers in Shear Flow -- 2.5 Transient Behavior of a Nine-Bead Chain in Elongational Flow -- 2.6 Conclusions and Perspectives -- List of Symbols and Abbreviations -- References -- 3 Tethered Polymer Chains Under Strong Flows: Stems and Flowers -- 3.1 Introduction -- 3.2 Chains Immersed in a Pure Solvent -- 3.3 Tethered Chains Immersed in a Polymer Solution -- 3.4 Tethered Chains in Poor Solvents -- 3.5 Tethered Chains Confined in a Slit -- 3.6 Concluding Remarks -- References -- 4 Osmotic Pressure in Solutions of Stretched Polymers -- 4.1 Introduction -- 4.2 Semi-Dilute Solution of Stretched Polymers -- 4.3 Discussion -- References -- 5 Stretching of Polyelectrolytes in Elongational Flow -- 5.1 Introduction -- 5.2 Experimental Evidence -- 5.3 Early Theoretical Approaches -- 5.4 Equilibrium Conformation of the Polyelectrolyte Chain -- 5.5 Stretching Transition in the Polyelectrolyte Chain -- 5.6 Conclusions and Discussion -- List of Symbols and Abbreviations -- References -- 6 Calculation of Flows with Large Elongational Components: CONNFFESSIT Calculation of the Flow of a FENE Fluid in a Planar 10:1 Contraction -- 6.1 Introduction -- 6.2 CONNFFESSIT -- 6.3 Geometry of the Planar Contraction Flow Problem -- 6.4 The Polymeric Fluid -- 6.5 The Time-Marching Procedure -- 6.6 Algorithms -- 6.7 Initial and Boundary Conditions -- 6.8 Continuum-Mechanical and Molecular Results -- 6.9 Summary -- List of Symbols and Abbreviations -- References -- 7 Polymer Solutions in Strong Stagnation Point Extensional Flows -- 7.1 Introduction -- 7.2 Theory and Modelling of Stretching Macromolecules -- 7.3 Experimental Realization -- 7.4 Chain Stretching in Dilute Solutions -- 7.5 Semi-Dilute Solution Behaviour -- 7.6 Extensional Viscometry -- 7.7 Thermomechanical Degradation -- 7.8 Conclusions -- References -- 8 Birefringence of Dilute PS Solutions in Abrupt Contraction Flow -- 8.1 Introduction -- 8.2 Realization of Abrupt Contraction Flow -- 8.3 Flow Birefringence Measurements -- 8.4 Experimental Results -- 8.5 Discussion -- 8.6 Prospects and Conclusions -- 8.6.1 Final Words -- Appendix A -- Appendix B -- Appendix C -- List of Symbols and Abbreviations -- References -- 9 The Hydrodynamics of a DNA Molecule in a Flow Field -- 9.1 Introduction -- 9.2 Calculation of the Drag Coefficient -- 9.3 Stretching Experiments with Longer DNA Molecules -- 9.4 Hydrodynamic Model for DNA -- 9.5 Simulation Results -- 9.6 Discussion -- Appendix: Model Validation -- List of Symbols and Abbreviations -- References -- 10 Single Polymers in Elongational Flows: Dynamic, Steady-State, and Population-Averaged Properties -- 10.1 Introduction -- 10.2 Previous Experimental Work -- 10.3 Experimental Technique -- 10.4 Experimental Results -- 10.5 Summary -- 10.6 Future Prospects -- List of Symbols and Abbreviations -- References -- 11 The Rheology of Polymer Solutions in Porous Media -- 11.1 Introduction -- 11.2 Fluid Dynamics Characterization of Porous Media Flows -- 11.3 Non-Newtonian Behavior in the Flow of Polymer Solutions Through Porous Media -- 11.4 Flow-Induced Degradation -- 11.5 Porous Media Flows of Polymer Blends and Cross-Linked Polymers in Solution -- 11.6 Concluding Remarks -- List of Symbols and Abbreviations -- References.
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|a Flexible Polymer Chain Dynamics in Elongational Flow fulfills a need by presenting the most important advances in the field of flexible polymer chains in "strong" flow in a single literature source. Although several excellent treatises on polymer dynamics have appeared over the years, most of them deal with polymer chains in the quiescent state or in simple shear flow. Elongational flow with an inherent low vorticity proves to be more efficient in extending polymer chains than simple shear flow and thus is more interesting from the point of view of basic (molecular chain dynamics at high deformation) and applied polymer science (rheology, fiber spinning, drag reduction, flow through porous media). In the two decades which followed the seminal "coil-stretching" model formulated by Prof. de Gennes in 1974, significant progress in the understanding of chain conformation in "strong" flow has been accomplished through a combination of advances in instrumentation, computation techniques and theoretical studies. In this volume, articles from leading specialists provide the reader with broad coverage of the different aspects of flexible polymer chains in elongational flow while identifiying directions and challenges for future studies.
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| 590 |
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|a Loaded electronically.
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| 590 |
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|a Electronic access restricted to members of the Holy Cross Community.
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| 650 |
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|a Polymers .
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| 650 |
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|a Condensed matter.
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| 650 |
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|a Optical materials.
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| 650 |
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|a Electronic materials.
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|a Physical chemistry.
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| 690 |
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|a Electronic resources (E-books)
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| 700 |
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|a Nguyen, Tuan Q.
|e editor.
|4 edt
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| 700 |
1 |
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|a Kausch, Hans-Henning.
|e editor.
|4 edt
|4 http://id.loc.gov/vocabulary/relators/edt
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| 710 |
2 |
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|a SpringerLink (Online service)
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| 830 |
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|a Springer eBook Collection.
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