Contribution of Clusters Physics to Materials Science and Technology From Isolated Clusters to Aggregated Materials

Contribution of Clusters Physics to Materials Science and Technology From Isolated Clusters to Aggregated Materials / edited by Joel Davenas, P.M. Rabette.

During the last decade there has been an increasing interest in clusters and small particles because of the peculiar proper­ ties induced by their large area to volume ratio. For that reason small particles are often considered as an intermediate state of matter at the border between atomic (or mole...

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Bibliographic Details
Corporate Author: SpringerLink (Online service)
Other Authors: Davenas, Joel (Editor), Rabette, P.M (Editor)
Format: eBook
Language:English
Published: Dordrecht : Springer Netherlands : Imprint: Springer, 1986.
Edition:1st ed. 1986.
Series:Nato Science Series E:, Applied Sciences, 104
Springer eBook Collection.
Subjects:
Condensed matter.
Solid state physics.
Spectroscopy.
Microscopy.
Materials science.
Electronic resources (E-books)
Online Access:Click to view e-book
Holy Cross Note:Loaded electronically.
Electronic access restricted to members of the Holy Cross Community.
Table of Contents:
  • Properties of Clusters in the Gas Phase
  • 1. Introduction
  • 2. Cluster production
  • 3. Mass spectrometrie detection
  • 4. Experiments on clusters in the gas phase
  • 5. Laser spectroscopy of free clusters
  • 6. Future developments
  • Metal Cluster Beams and Electron Diffraction: Deviations from the Bulk States of Matter
  • 1. Introduction
  • 2. The cluster nucleation process
  • 3. Cluster beams
  • 4. Cluster electron diffraction
  • 5. Metal cluster results
  • Generation of Beams of Refractory Metal Clusters
  • An Introduction to the Field of Catalysis by Molecular Clusters
  • 1. An introduction to molecular clusters
  • 2. Catalysis by molecular clusters
  • Quantum Chemistry for Metal Clusters
  • 1. Generalities — cluster science
  • 2. Quantum chemical methods
  • 3. Comparisons of Hartree-Fock with X? (LSD) results
  • 4. Electronic and magnetic structure of transition metal clusters
  • 5. Concluding remarks — need for experiments on isolated clusters
  • Electronic Structure of Metal Clusters
  • 1. Introduction
  • 2. Results
  • 3. Experimental results
  • Characterization of Supported Metal Particles in Heterogeneous Catalysts: I. Studies of high surface area materials
  • 1. Introduction
  • 2. Strategies for characterization of metal particles on on high surface area supports
  • 3. X-ray diffraction and scattering
  • 4. Extended X-ray absorption fine structure
  • 5. Mossbauer spectroscopy
  • 6. Magnetic susceptibility
  • 7. Ferromagnetic resonance
  • 8. Vibrational spectroscopy
  • Characterization of Supported Metal Particles in Heterogeneous Catalysts: II. Studies of low surface area, model materials
  • 1. Introduction
  • 2. Strategies for characterization of metal particles on low surface area, model supports
  • 3. Experimental techniques
  • 4. Applications of studies using model supported metal samples
  • 5. Concluding remarks
  • Peculiar Aspects of Heterogeneous Nucleation and Growth Processes Related to Metal Supported Catalyst
  • 1. Introduction
  • 2. Kevnotes for heterogeneous nucleation
  • 3. Mass transfer mechanisms
  • 4. Epitaxy post nucleation phenomenon
  • 5. Miscellaneous
  • Formation, Action, and Properties of Clusters in the Photographic Process
  • 1. Introduction
  • 2. Basic principles of the photographic process
  • 3. Theory of the photographic process
  • 4. Outlook
  • Formation of Clusters in Bulk Materials
  • 1. Introduction
  • 2. Metal-excess alkali halides
  • 3. Experimental methods for the study of colloids
  • 4. Nucleation of colloids from F centres
  • 5. Growth of colloids
  • 6. Particle coarsening
  • 7. Formation of clusters by irradiation
  • 8. Summary
  • Optical Properties of Small Particles in Insulating Matrices
  • 1. Introduction
  • 2. Optical material properties of small particles
  • 3. Optical extinction and dispersion of one particle
  • 4. Optical properties of systems of many particles
  • to Percolation Theory
  • 1. Two examples
  • 2. Formal definition — Site percolation — Bond percolation
  • 3. Definition and behaviour of the characteristic quantities
  • 4. Thermodynamic analogy
  • 5. Scaling laws
  • 6. Exact results
  • 7. Approximate results
  • 8. The exponent of the conductivity
  • 9. Percolation and macroscopic random media
  • Electronic and Transport Properties of Granular Materials
  • I. Effective medium theories of transport in inhomogeneous materials
  • II. Specific inhomogeneous materials Morrel H. Cohen
  • III. The origins of clustering Morrel H. Cohen
  • Optical Properties and Solar Selectivity of Metal-Insulator Composites
  • 1. Introduction
  • 2. Effective medium theories
  • 3. Bounds on the effective dielectric permeability
  • 4. Size limits for validity of effective medium theories
  • 5. Case study one: optical properties and solar selectivity of coevaporated Co-Al2O3 films
  • 6. Case study two: electrolytically coloured anodic Co-Al2O3 coatings
  • 7. Summary and remarks
  • Adhesion and Sintering of Small Particles
  • 1. Introduction
  • 2. Production of particles
  • 3. General observations
  • 4. Dynamics aspects of contact
  • 5. Other aspects of adhesion
  • 6. Sintering of small particles
  • 7. Conclusion
  • Physics on the Beach or the Theory of Windsurfing.

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