Nuclear Magnetic Resonance Spectroscopy of Boron Compounds

Nuclear Magnetic Resonance Spectroscopy of Boron Compounds by Heinrich Nöth, Bernd Wrackmeyer.

The revolutionary impetus of the NMR methods in organic chemistry has parallels in the field of boron chemistry. lIB NMR spectroscopy provided a basis for the elucida­ tion of structures and reactions of the boron hydrides. However, although many studies have been carried out with the higher boranes...

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Bibliographic Details
Main Authors: Nöth, Heinrich (Author), Wrackmeyer, Bernd (Author)
Corporate Author: SpringerLink (Online service)
Format: eBook
Language:English
Published: Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 1978.
Edition:1st ed. 1978.
Series:NMR Basic Principles and Progress, 14
Springer eBook Collection.
Subjects:
Spectroscopy.
Analytical chemistry.
Inorganic chemistry.
Electronic resources (E-books)
Online Access:Click to view e-book
Holy Cross Note:Loaded electronically.
Electronic access restricted to members of the Holy Cross Community.
Table of Contents:
  • 1 Introduction and Scope
  • 1.1. Application of 11 B NMR Spectroscopy
  • 1.2. Scope
  • Literature to Chapter 1
  • 2 Nuclear Magnetic Properties of Boron
  • 2.1. The Isotopes 10 B,11 B
  • 2.2. Information from Boron NMR Data
  • 2.3. Chemical Shifts
  • 2.4. Spin-Spin Coupling
  • Literature to Chapter 2
  • 3 11B NMR of Two-Coordinate Boron
  • 4 11B Chemical Shifts of Three-Coordinate Boron
  • 4.1. Survey of Substituent Effects
  • 4.2. Triorganylboranes
  • 4.3. Halogenoboranes
  • 4.4. Boranes with Boron-Oxygen Bonds
  • 4.5. Boranes with Boron-Sulfur Bonds
  • 4.6. Boranes with Boron-Selenium Bonds
  • 4.7. Boranes with Boron-Nitrogen Bonds
  • 4.8. Diboron and Polyboron Compounds
  • 4.9. Boranes with Boron-Hydrogen Bonds
  • 4.10. Boranes with Boron-Silicon, Boron-Germanium, Boron-Tin, and Boron-Lead Bonds
  • 5 11B NMR of Transition Metal Boron Compounds
  • 6 11B NMR of Diborane and Derivatives
  • 6.1. Diborane
  • 6.2. Organyldiboranes
  • 6.3. µ-Substituted Diboranes
  • 6.4. Heptahydrodiborates and µ-Substituted Derivatives
  • 7 11B NMR of Tetracoordinate Boron
  • 7.1. Metal Tetrahydroborates
  • 7.2. Substituted Metal Tetrahydroborates
  • 7.3. Metal Borates MBX4 and [BX4-nYn]
  • 7.4. Donor-Acceptor Complexes
  • 8 Spin-Spin Coupling Constants nJ(11 BX)
  • 8.1. Spin-Spin Coupling Between Boron and Hydrogen
  • 8.2. Boron-Boron Coupling Constants
  • 8.3. Coupling Constants of Boron and Group IV Elements
  • 8.4. Spin-Spin Coupling Between Boron and Group V Elements
  • 8.5. Coupling Between Boron and Group VI Elements
  • 8.6. Coupling Between Boron and Fluorine
  • 8.7. Spin-Spin Coupling Between Boron and Transition Metals
  • 9 Tables of 11B-NMR Data
  • 9.1. Remarks on the Organization of the Tables
  • 9.2. List of Tables, Including Structural Symbols
  • 9.3. Tables
  • 9.4. CA Formula Index
  • References
  • Author Index.

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