|
|
|
|
| LEADER |
00000nam a22000005i 4500 |
| 001 |
b3296562 |
| 003 |
MWH |
| 005 |
20191026012225.0 |
| 007 |
cr nn 008mamaa |
| 008 |
170214s2017 gw | s |||| 0|eng d |
| 020 |
|
|
|a 9783319518077
|
| 024 |
7 |
|
|a 10.1007/978-3-319-51807-7
|2 doi
|
| 035 |
|
|
|a (DE-He213)978-3-319-51807-7
|
| 050 |
|
4 |
|a E-Book
|
| 072 |
|
7 |
|a PNND
|2 bicssc
|
| 072 |
|
7 |
|a SCI013040
|2 bisacsh
|
| 072 |
|
7 |
|a PNND
|2 thema
|
| 100 |
1 |
|
|a Hadlington, Terrance John.
|e author.
|4 aut
|4 http://id.loc.gov/vocabulary/relators/aut
|
| 245 |
1 |
0 |
|a On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
|h [electronic resource] /
|c by Terrance John Hadlington.
|
| 250 |
|
|
|a 1st ed. 2017.
|
| 264 |
|
1 |
|a Cham :
|b Springer International Publishing :
|b Imprint: Springer,
|c 2017.
|
| 300 |
|
|
|a XIX, 243 p. 170 illus., 59 illus. in color.
|b online resource.
|
| 336 |
|
|
|a text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a computer
|b c
|2 rdamedia
|
| 338 |
|
|
|a online resource
|b cr
|2 rdacarrier
|
| 347 |
|
|
|a text file
|b PDF
|2 rda
|
| 490 |
1 |
|
|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
|
| 490 |
1 |
|
|a Springer eBook Collection
|
| 505 |
0 |
|
|a General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry.
|
| 520 |
|
|
|a This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal–metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry.
|
| 590 |
|
|
|a Loaded electronically.
|
| 590 |
|
|
|a Electronic access restricted to members of the Holy Cross Community.
|
| 650 |
|
0 |
|a Organometallic chemistry .
|
| 650 |
|
0 |
|a Catalysis.
|
| 650 |
|
0 |
|a Inorganic chemistry.
|
| 690 |
|
|
|a Electronic resources (E-books)
|
| 710 |
2 |
|
|a SpringerLink (Online service)
|
| 773 |
0 |
|
|t Springer eBooks
|
| 830 |
|
0 |
|a Springer Theses, Recognizing Outstanding Ph.D. Research,
|x 2190-5053
|
| 830 |
|
0 |
|a Springer eBook Collection.
|
| 856 |
4 |
0 |
|u https://holycross.idm.oclc.org/login?auth=cas&url=https://doi.org/10.1007/978-3-319-51807-7
|3 Click to view e-book
|t 0
|
| 907 |
|
|
|a .b3296562x
|b 04-18-22
|c 02-26-20
|
| 998 |
|
|
|a he
|b 02-26-20
|c m
|d @
|e -
|f eng
|g gw
|h 0
|i 1
|
| 912 |
|
|
|a ZDB-2-CMS
|
| 950 |
|
|
|a Chemistry and Materials Science (Springer-11644)
|
| 902 |
|
|
|a springer purchased ebooks
|
| 903 |
|
|
|a SEB-COLL
|
| 945 |
|
|
|f - -
|g 1
|h 0
|j - -
|k - -
|l he
|o -
|p $0.00
|q -
|r -
|s b
|t 38
|u 0
|v 0
|w 0
|x 0
|y .i22097247
|z 02-26-20
|
| 999 |
f |
f |
|i 0bf73c7b-1b2e-5d28-994b-e61e6f68649f
|s d91ecd8d-0267-530f-97fb-e5121561e6bb
|t 0
|
| 952 |
f |
f |
|p Online
|a College of the Holy Cross
|b Main Campus
|c E-Resources
|d Online
|t 0
|e E-Book
|h Library of Congress classification
|i Elec File
|