Alkali-doped fullerides : narrow-band solids with unusual properties / Olle Gunnarsson.

Alkali-doped fullerides have attracted strong interest since their production became possible about fifteen years ago. This book presents work which may solve intriguing problems arising from a variety of remarkable properties. For example, these solids are superconductors with high transition tempe...

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Bibliographic Details
Main Author: Gunnarsson, Olle
Format: eBook
Language:English
Published: River Edge, N.J. : World Scientific, ©2004.
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Online Access:Click for online access

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245 1 0 |a Alkali-doped fullerides :  |b narrow-band solids with unusual properties /  |c Olle Gunnarsson. 
260 |a River Edge, N.J. :  |b World Scientific,  |c ©2004. 
300 |a 1 online resource (xvii, 282 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
347 |a data file  |2 rda 
504 |a Includes bibliographical references (pages 261-277) and index. 
588 0 |a Print version record. 
505 0 |a Ch. 1. Structural properties. 1.1. Structure of the C[symbol] molecule. 1.2. Structures of some solids -- ch. 2. Models and parameters. 2.1. Models of hopping. 2.2. Coulomb interaction. 2.3. Electron-phonon interaction. 2.4. Electron-plasmon coupling. 2.5. Current operator -- ch. 3. Phonons and electron-phonon coupling strength. 3.1. Intramolecular modes. 3.2. Alkali phonons. 3.3. Librations. 3.4. Intermolecular modes -- ch. 4. Interacting electron-phonon system. 4.1. Free molecules. 4.2. Spectral functions in metallic fullerenes. 4.3. Model calculation -- ch. 5. Electronic structure. 5.1. Band structure calculations. 5.2. Tight-binding calculations. 5.3. GW calculations. 5.4. Susceptibility. 5.5. Specific heat. 5.6. Density of states. 5.7. Hall effect. 5.8. Photoemission -- ch. 6. Plasmons. 6.1. Experimental results. 6.2. Plasmon dispersion. 6.3. Plasmon broadening -- ch. 7. Metal-insulator transition. 7.1. Experimental results and U/W ratio. 7.2. Calculational approach: Projection Quantum Monte Carlo method. 7.3. Degeneracy dependence. 7.4. Filling dependence. 7.5. Lattice structure dependence. 7.6. Effects of electron-phonon and Hund's rule coupling. 7.7. Effects of noncubic lattice structure -- ch. 8. Electrical resistivity. 8.1. Mean free path. 8.2. Resistivity saturation. 8.3. Experimental results. 8.4. Boltzmann theory of resistivity. 8.5. Beyond the Boltzmann equation. 8.6. Different classes of saturation behavior -- ch. 9. Superconductivity. 9.1. Experimental results. 9.2. Retardation effects and Coulomb pseudopotential. 9.3. Local pairing. 9.4. Electronic mechanism. 9.5. Isotope effect. 9.6. Comparison with experiments -- ch. 10. Discussion. 
520 |a Alkali-doped fullerides have attracted strong interest since their production became possible about fifteen years ago. This book presents work which may solve intriguing problems arising from a variety of remarkable properties. For example, these solids are superconductors with high transition temperatures, although the similarity between the electronic and phonon energy scales should suppress superconductivity. Moreover, the Ioffe-Regel condition for electrical conductivity is strongly violated. The book shows why superconductivity is nevertheless possible, owing to a local pairing mechanism. The Ioffe-Regel condition is derived quantum-mechanically, and it is explained why the underlying assumptions are violated for fullerides and high-Tc cuprates, for example. The book treats electronic and transport properties, reviewing theoretical and experimental results. It focuses on superconductivity, electrical conductivity and metalinsulator transitions, emphasizing the electron-electron and electron-phonon interactions as well as the John-Teller effect. 
546 |a English. 
650 0 |a Superconductors. 
650 0 |a Superconductivity. 
650 0 |a Electric conductivity. 
650 0 |a Metal-insulator transitions. 
650 0 |a Electron-electron interactions. 
650 0 |a Electron-phonon interactions. 
650 0 |a Jahn-Teller effect. 
650 7 |a superconductor.  |2 aat 
650 7 |a electrical conductivity.  |2 aat 
650 7 |a TECHNOLOGY & ENGINEERING  |x Superconductors & Superconductivity.  |2 bisacsh 
650 7 |a Electric conductivity  |2 fast 
650 7 |a Electron-electron interactions  |2 fast 
650 7 |a Electron-phonon interactions  |2 fast 
650 7 |a Jahn-Teller effect  |2 fast 
650 7 |a Metal-insulator transitions  |2 fast 
650 7 |a Superconductivity  |2 fast 
650 7 |a Superconductors  |2 fast 
650 7 |a Supraconducteurs.  |2 rvm 
650 7 |a Supraconductivité.  |2 rvm 
650 7 |a Conduction électrique.  |2 rvm 
650 7 |a Transitions métal-isolant.  |2 rvm 
650 7 |a Interactions électron-électron.  |2 rvm 
650 7 |a Interactions électron-phonon.  |2 rvm 
650 7 |a Jahn-Teller, Effet.  |2 rvm 
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