Carbon-centered free radicals and radical cations : structure, reactivity, and dynamics / edited by Malcolm D. Forbes.

The chemistry and biochemistry of reactive intermediates is central to modern mechanistic and quantitative understanding of organic chemistry and biochemistry. The only comprehensive review to cover carbon-centered radical intermediates and their role(s) in chemistry and biochemistry, Carbon-Centere...

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Bibliographic Details
Other Authors: Forbes, Malcolm D. E., 1960-
Format: Electronic
Published: Hoboken, NJ : Wiely, ©2010.
Series:Wiley series on reactive intermediates in chemistry and biology.
Online Access:Click for online access
Table of Contents:
  • CARBON-CENTERED FREE RADICALS AND RADICAL CATIONS; CONTENTS; About the Volume Editor; Preface to Series; Introduction; Contributors; 1. A Brief History of Carbon Radicals; 2. Intermolecular Radical Additions to Alkynes: Cascade-Type Radical Cyclizations; 3. Radical Cation Fragmentation Reactions in Organic Synthesis; 4. Selectivity in Radical Cation Cycloadditions; 5. The Stability of Carbon-Centered Radicals; 6. Interplay of Stereoelectronic Vibrational and Environmental Effects in Tuning Physicochemical Properties of Carbon-Centered Radicals.