Solid state chemistry / D.K. Chakrabarty.

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Bibliographic Details
Main Author: Chakrabarty, D. K.
Format: eBook
Language:English
Published: Tunbridge Wells : New Academic Science, ©2012.
Edition:2nd ed.
Subjects:
Online Access:Click for online access
Table of Contents:
  • Cover
  • Preface to the Second Edition
  • Preface to the First Edition
  • Contents
  • Chapter-1. The Crystal Structure
  • 1.1 Introduction
  • 1.2 Crystal Planes and Miller Indices
  • 1.3 Diffraction of X-Rays
  • 1.3.1 Braggâ€?s Law of Diffraction
  • 1.4 Reciprocal Lattice
  • 1.5 Powder Method
  • 1.5.1 Debye-Scherrer Method
  • 1.5.2 The Powder Diffractometer
  • 1.5.3 Indexing the Powder Patterns
  • 1.5.4 Use of X-ray Powder Patterns
  • 1.6 Crystal Defects
  • 1.6.1 Point Defects
  • 1.6.2 Defect Equations
  • 1.6.3 Vacancy Concentration in a Metal
  • 1.6.4 Schottky Defect Concentration in an Ionic Crystal1.6.5 Frenkel Defect Concentration
  • 1.6.6 Dislocations
  • 1.6.7 Plane Defects or Grain Boundaries
  • Suggested Reading
  • Chapter-2. Bonding in Solids
  • 2.1 Introduction
  • 2.2 van der Waals Forces
  • 2.3 Covalency
  • 2.4 Ionic Bond
  • 2.4.1 Effect of Polarization
  • 2.4.2 Empirical Lattice Energy Equation
  • 2.5 Ionic Radii
  • 2.6 Bonding in Metals
  • 2.6.1 Paulingâ€?s Valence Bond Method
  • 2.7 Types of Solids
  • 2.8 Mechanical Properties of Solids
  • Suggested Reading
  • Chapter-3. Structure of Solids3.1 Close Packing of Atoms
  • 3.2 Structure of Metals
  • 3.2.1 Body Centred Cubic Metals
  • 3.3 Structure of Binary and Ternary Compounds
  • 3.3.1 Octahedral and Tetrahedral Voids
  • 3.3.2 Radius Ratio Rule
  • 3.4 Structure of Ionic Crystals
  • 3.4.1 Crystals with Stoichiometry MX
  • 3.4.2 Crystals with Stoichiometry MX2
  • 3.4.3 The Spinel Structure
  • 3.4.4 The Perovskite Structure
  • 3.4.5 Specific Defect Structures
  • Suggested Reading
  • Chapter-4. Nonstoichiometry in Solids
  • 4.1 Thermodynamic Considerations
  • 4.1.1 Oxygen Deficient Oxide4.1.2 Metal Deficient Oxides
  • 4.2 Classification of Non-stoichiometry
  • 4.2.1 Small Deviation from Stoichiometry
  • 4.2.2 Large Deviation from Stoichiometry
  • 4.3 Superlattice Ordering of Defects
  • 4.4 Shear Structure
  • Suggested Reading
  • Chapter-5. Phase Transition in Solids
  • 5.1 Thermodynamic Considerations
  • 5.2 Types of Phase Transitions
  • 5.2.1 Order-disorder Transformation
  • 5.2.2 Martensitic Transition
  • 5.2.3 Polymorphic Transformation
  • 5.2.4 Recrystallization
  • 5.2.5 Polytypes
  • 5.3 Phase Rule
  • 5.4 Two-Component System5.4.1 Solid-liquid Phase Diagram
  • 5.5 Rate of Phase Transition
  • 5.6 Sintering
  • 5.7 Growing Single Crystals
  • 5.7.1 Practical Methods of Growing Crystals
  • Suggested Reading
  • Chapter-6. Reactions of Solids
  • 6.1 Thermal Decomposition
  • 6.1.1 Laws of Nucleation and Growth
  • 6.1.2 Some Type I Reactions
  • 6.1.3 Reaction between Two Solids
  • 6.1.4 Improving Solid-Solid Reactions
  • 6.2 Diffusion in Solids
  • 6.2.1 Atomic Approach
  • 6.2.2 Diffusion Equation
  • 6.2.3 The Continuum Method
  • Suggested Reading