Advanced organic chemistry

Advanced organic chemistry / Deepa Sharma.

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Bibliographic Details
Main Author: Sharma, Deepa
Format: eBook
Language:English
Published: Tunbridge Wells : New Academic Science, ©2012.
Subjects:
Chemistry, Organic.
Chemistry.
organic chemistry.
chemistry.
Chemistry
Chemistry, Organic
Online Access:Click for online access
Table of Contents:
  • Cover
  • Preface
  • Acknowledgements
  • Contents
  • Section-I Fundamentals of Organic Chemistry
  • Chapter 1 Atomic Bonding
  • 1.1 Introduction
  • 1.2 Valence Bond Theory
  • 1.3 Molecular Orbital Theory (MOT)
  • 1.3.1 Formation of Bonding Molecular Orbital (Additive Overlapping of Two Atomic Orbitals)
  • 1.3.2 Formation of Antibonding Molecular Orbital (ABMO)(Subtractive Overlapping of Two Atomic Orbitals)
  • 1.3.3 Rules for Linear Combination of Atomic Orbitals
  • 1.3.4 Rules for Filling up of Molecular Orbitals
  • 1.3.5 MO Diagram
  • 1.3.6 Bond Order or Bond Multiplicity1.3.7 Difference between Atomic Orbitals and Molecular Orbitals
  • 1.3.8 Similarities between Atomic Orbitals and Molecular Orbitals
  • 1.4 VSEPR Theory
  • 1.4.1 Postulates of VSEPR Theory
  • 1.5 Metallic Crystal
  • 1.5.1 Factors Favouring the Formation of Metallic Bond
  • 1.5.2 Nature of Metallic Bond
  • 1.5.3 Some of the Physical Properties of Metals and their Explanation on the Basis of Electron-gas Theory
  • 1.6 Hydrogen Bond
  • 1.6.1 What is Hydrogen Bond?
  • 1.6.2 Types of Hydrogen Bonding
  • 1.6.3 Nature and Formation of Hydrogen Bond1.6.4 Conditions for the Formation of Hydrogen Bond
  • 1.6.5 Strength of H-bond
  • 1.6.6 Effect of Hydrogen Bonding on the Physical Properties of the Compounds Containing Hydrogen Bonds
  • Chapter 2 Stereochemistry
  • 2.1 Isomerism
  • 2.1.1 Structural Isomerism
  • 2.2 Stereoisomerism
  • 2.2.1 General Terms Encountered in Stereochemistry or Causes of Optical Isomerism
  • 2.3 Optical Isomerism and Chirality
  • 2.3.1 Optical Activity
  • 2.3.2 The Polarimeter
  • 2.3.3 Calculation of Number of Optical Isomers
  • 2.4 Compounds Containing More Than One Chiral Centres 2.5 Specific Configuration for Compounds Containing More than one Chiral Centre
  • 2.6 Geometrical Isomerism or CIS-Trans Isomerism
  • 2.7 Racemization
  • 2.8 Walden Inversion
  • 2.9 To Assign 'E-Z' Configuration and 'R-S' Configuration on the Basis of Sequence Rule
  • 2.10 Conversion of 3-Dimensional Structures to Fischer Projection Formula
  • 2.11 Optically Active Compounds Without Chiral Centre
  • 2.11.1 Chirality in Allenes
  • 2.11.2 Chirality in Spirans
  • 2.11.3 Chirality in Biphenyls
  • 2.12 Conformational Analysis 2.12.1 Conformers of Ethane
  • 2.12.2 Conformations of n-Butane
  • 2.12.3 Conformations of 1,2-Dichloro Ethane
  • Chapter 3 Reaction Intermediates and Factors Affecting Reactivity
  • 3.1 Carbonium Ion or Carbocations
  • 3.1.1 Classification of Carbonium Ions
  • 3.1.2 Formation of Carbonium Ions
  • 3.1.3 Order of Stability of Carbonium Ions
  • 3.1.4 Structure of Carbonium Ion
  • 3.2 Carbanions
  • 3.2.1 Classification of Carbanions
  • 3.2.2 Structure of Carbanions
  • 3.2.3 Stability of Carbanions

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