Chemistry and Technology of Emulsion Polymerisation.

Chemistry and Technology of Emulsion Polymerisation.

Chemistry and Technology of Emulsion Polymerisation 2e provides a practical and intuitive explanation of emulsion polymerization, in combination with both conventional and controlled radical polymerization. For those working in industry, coupling theory with everyday practice can be difficult. By ca...

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Bibliographic Details
Main Author: Van Herk, A. M.
Format: eBook
Language:English
Published: Hoboken : Wiley, 2013.
Edition:2nd ed.
Subjects:
Technology.
TECHNOLOGY & ENGINEERING > Chemical & Biochemical.
Technology
Online Access:Click for online access
Table of Contents:
  • Chemistry and Technology of Emulsion Polymerisation Second Edition; Contents; List of Contributors; Abbreviations; List of Frequently Used Symbols; Introduction to the Second Edition; Introduction to the First Edition; 1 Historic Overview; 1.1 The Early Stages; 1.2 The Second Half of the Twentieth Century; 1.2.1 Product Development; 1.2.2 Kinetic Theory; 1.2.3 Emulsion Polymerisation in Monomer Droplets; 1.2.4 Industrial Process Control and Simulation; 2 Introduction to Radical (Co)Polymerisation; 2.1 Mechanism of Free Radical Polymerisation.
  • 2.2 Rate of Polymerisation and Development of Molecular Mass Distribution2.2.1 Rate of Polymerisation; 2.2.2 Kinetic Chain Length; 2.2.3 Chain Length Distribution; 2.2.4 Temperature and Conversion Effects; 2.3 Radical Transfer Reactions; 2.3.1 Radical Transfer Reactions to Low Molecular Mass Species; 2.3.2 Radical Transfer Reactions to Polymer; 2.4 Radical Copolymerisation; 2.4.1 Derivation of the Copolymerisation Equation; 2.4.2 Types of Copolymers; 2.4.3 Polymerisation Rates in Copolymerisations; 2.5 Controlled Radical Polymerisation; 3 Emulsion Polymerisation; 3.1 Introduction.
  • 3.2 General Aspects of Emulsion Polymerisation3.3 Basic Principles of Emulsion Polymerisation; 3.4 Particle Nucleation; 3.5 Particle Growth; 3.5.1 The Zero-One and Pseudo-Bulk Dichotomy; 3.5.2 Zero-One Kinetics; 3.5.3 Pseudo-Bulk Kinetics; 3.5.4 Systems between Zero-One and Pseudo-Bulk; 3.6 Ingredients in Recipes; 3.6.1 Monomers; 3.6.2 Initiators; 3.6.3 Surfactants; 3.6.4 Other Ingredients; 3.7 Emulsion Copolymerisation; 3.7.1 Monomer Partitioning in Emulsion Polymerisation; 3.7.2 Composition Drift in Emulsion Co- and Terpolymerisation; 3.7.3 Process Strategies in Emulsion Copolymerisation.
  • 3.8 Particle Morphologies3.8.1 Core-Shell Morphologies; 4 Emulsion Copolymerisation, Process Strategies; 4.1 Introduction; 4.2 Monomer Partitioning; 4.2.1 Slightly and Partially Water Miscible Monomers; 4.2.2 Consequences of Monomer Partitioning for the Copolymer Composition; 4.3 Process Strategies; 4.3.1 Batch Operation; 4.3.2 Semi-Batch Operation; 4.3.3 Control Opportunities; 5 Living Radical Polymerisation in Emulsion and Miniemulsion; 5.1 Introduction; 5.2 Living Radical Polymerisation; 5.2.1 General/Features of a Controlled/Living Radical Polymerisation; 5.2.2 Reversible Termination.
  • 5.2.3 Reversible Chain Transfer5.3 Nitroxide-Mediated Polymerisation in Emulsion and Miniemulsion; 5.3.1 Introduction; 5.3.2 Control of Molar Mass and Molar Mass Distribution; 5.3.3 Synthesis of Block and Random or Gradient Copolymers via (Mini)Emulsion Polymerisation; 5.3.4 Surfactant-Free Emulsion Polymerisation Using the Polymerisation-Induced Self-Assembly Technique; 5.4 ATRP in Emulsion and Miniemulsion; 5.4.1 Introduction; 5.4.2 Direct ATRP; 5.4.3 Reverse ATRP; 5.4.4 Next Generation ATRP Techniques: SRNI and AGET; 5.4.5 Some Concluding Remarks on ATRP in Emulsion.

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