1,1'-Binaphthyl-Based Chiral Materials : Our Journey.

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Bibliographic Details
Main Author: Lin, Pu
Format: eBook
Published: Singapore : World Scientific Publishing Company, 2009.
Online Access:Click for online access


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100 1 |a Lin, Pu. 
245 1 0 |a 1,1'-Binaphthyl-Based Chiral Materials :  |b Our Journey. 
260 |a Singapore :  |b World Scientific Publishing Company,  |c 2009. 
300 |a 1 online resource (346 pages) 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
588 0 |a Print version record. 
520 |a Chiral materials have been studied in the Department of Chemistry at the University of Virginia for applications in areas like asymmetric catalysis, enantioselective fluorescent sensing, and optical/electrical materials. Optically active 1,1'-binaphthyl molecules are used to build novel chiral polymers, dendrimers, macrocycles, and acyclic molecules. 1,1'-Binaphthyl molecules are chosen because of their remarkably stable chiral configuration as well as their high asymmetric inductions in many processes. In this book, both the fundamental knowledge about the 1,1'-binaphthyl molecules and the sy. 
505 0 |a Preface; Contents; References; 1. Introduction About 1,1 -Binaphthyls; References; 2. Main Chain Chiral-Conjugated Polymers; 2.1. Introduction About Chiral-Conjugated Polymers; 2.2. Binaphthyl-Based Polyarylenevinylenes; 2.3. Binaphthyl-Based Polyarylenes; 2.4. Binaphthyl-Based Polyaryleneethynylenes; 2.5. Binaphthyl-Thiophene Copolymers; 2.5.1. Copolymerization of Binaphthyl and Oligothiophene Monomers; 2.5.2. Electroluminescence Study; 2.6. Copolymers of BINAM and Thiophene-Containing Conjugated Linkers; 2.7. Polybinaphthyls Without Conjugated Linkers. 
505 8 |a 2.7.1. Using Nickel Complexes to Promote Polymerization212.7.2. Synthesis of the Binaphthyl-Based Polydendrimers by Using Ni Complexes to Promote Polymerization23; 2.7.3. Using the Suzuki Coupling Reaction for Polymerization21b; 2.7.4. Electroluminescence Study of the Polybinaphthyls26; 2.8. Propeller-Like Polybinaphthyls; 2.8.1. Synthesis of the Propeller-Like Polymers Derived from BINOL27,28; 2.8.2. Synthesis of the Propeller-Like Polymers Derived from BINAM31; 2.8.3. Study of the Non-linear Optical Properties of the Propeller-Like Polymers32; 2.9. Dipole-Oriented Propeller-Like Polymers. 
505 8 |a 2.10. Binaphthyl-Based Polysalophens2.11. Helical Ladder Polybinaphthyls; References; 3. Polybinaphthyls in Asymmetric Catalysis; 3.1. Introduction about Chiral Polymers in Asymmetric Catalysis; 3.2. Synthesis of Major-Groove Poly(BINOL)s; 3.2.1. Synthesis of Polybinaphthyls with Various Protecting Groups5; 3.2.2. Hydrolysis of the Polybinaphthyls to Generate Poly(BINOL)s5; 3.2.3. Synthesis of Poly(BINOL)s Containing Alkyl-Substituted Phenylene Linkers6; 3.3. Application of the Major-Groove Poly(BINOL)s to Catalyze the Mukaiyama Aldol Reaction. 
505 8 |a 3.4. Application of the Major-Groove Poly(BINOL)s to Catalyze the Hetero-Diels-Alder Reaction3.5. Using the Ti(IV) Complex of the Major-Groove Poly(BINOL) to Catalyze the Diethylzinc Addition to Aldehydes; 3.6. Synthesis of the Minor-Groove Poly(BINOL)s; 3.7. Application of the Major- and Minor-Groove Poly(BINOL)s to Catalyze the Asymmetric Organozinc Addition to Aldehydes; 3.7.1. Asymmetric Diethylzinc Addition to Aldehydes Catalyzed by the Poly(BINOL)s; 3.7.2. Study of the Reactions of the Minor-Groove Poly(BINOL) and a Few Monomeric BINOL Derivatives with Diethylzinc. 
650 0 |a Chirality. 
650 0 |a Asymmetric synthesis. 
650 0 |a Molecular theory. 
650 7 |a Asymmetric synthesis  |2 fast 
650 7 |a Chirality  |2 fast 
650 7 |a Molecular theory  |2 fast 
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776 0 8 |i Print version:  |z 9781848164116 
856 4 0 |u https://ebookcentral.proquest.com/lib/holycrosscollege-ebooks/detail.action?docID=1681373  |y Click for online access 
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