Organic reaction mechanisms / Raj K. Bansal.

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Bibliographic Details
Main Author: Bansal, Raj K. (Author)
Format: eBook
Language:English
Published: Kent [England] : New Academic Science Limited, 2013.
Edition:Fourth edition.
Subjects:
Online Access:Click for online access
Table of Contents:
  • 2.5 Consecutive Reactions 2.6 Parallel or Concurrent Reactions ; 2.7 Reaction Rate Theory ; 2.8 Temperature Dependence of Rate Constant ; 2.9 Reaction Intermediates ; 2.10 Principle of Microscopic Reversibility ; 2.13 Chemical Evidence For Reaction Mechanisms ; 2.14 Kinetic Isotope Effects ; References ; Review Problems ; Chapter 3 Concept of Acids and Bases ; 3.1 Brönsted-Lowry Concept ; 3.2 Ionization of Acids and Bases ; 3.3 Lewis Concept of Acids and Bases ; 3.4 Acidity Function ; 3.5 Catalysis ; 3.6 Acid-Base Catalysis ; 3.7 Brönsted Relation.
  • 3.8 Hard and Soft Acids and Bases References ; Review Problems ; Chapter 4 Nucleophilic Displacement Reactions ; 4.1 Substitution Nucleophilic Bimolecular (SN2) ; 4.2 Substitution Nucleophilic Unimolecular (SN1) ; 4.3 Substitution at Bridgehead Halides ; 4.4 Isotope Effects In Substitution Reactions ; 4.5 Solvent Effects In Substitution Reactions ; 4.6 Salt Effects in Substitution Reactions ; 4.7 Ion-Pair Mechanism for SN1 Reactions ; 4.8 Substitution Nucleophilic Internal (SNi) ; 4.9 Substitution at Allylic and Allylenic Carbon Atom.
  • 4.10 Special Cases in Substitution Reactions 4.11 Reactivity in Cyclic Strained Compounds ; 4.12 The Bridgehead Carbocation Controversy ; References ; Review Problems ; Chapter 5 Organic Preparative Reactions ; 5.1 The Baeyer-Villiger Oxidation ; 5.2 The Meerwein-Ponndorf-Verley Reduction ; 5.3 The Clemmensen Reduction ; 5.4 The Wolff-Kishner Reduction ; 5.5 The Birch Reduction ; 5.6 The Aldol Condensation ; 5.7 The Benzoin Condensation ; 5.8 The Claisen Ester Condensation ; 5.9 The Darzens Condensation ; 5.10 The Perkin Condensation ; 5.11 The Hunsdiecker Reaction.
  • 5.12 Grignard Reagents 5.13 Carbenes ; 5.14 The Wittig Reaction ; 5.15 Enamines ; 5.16 The Mannich Reaction ; 5.17 The Diels-Alder Reaction ; References ; Review Problems ; Chapter 6 Free Radical Reactions ; 6.1 Geometry of Free Radicals ; 6.2 Stability of Free Radicals ; 6.3 The Detection of Free Radicals ; 6.4 Production of Free Radicals ; 6.5 Properties of Free Radicals ; 6.6 Types of Free Radical Reactions ; 6.7 Radical Halogenation of Hydrocarbons ; 6.8 Autoxidation ; 6.9 Free Radical Rearrangements ; 6.10 Radical Cyclization and Ring Expansion.