Asymmetric Synthesis of Three-Membered Rings.

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Bibliographic Details
Main Author: Pellissier, Hélène
Other Authors: Lattanzi, Alessandra, Dalpozzo, Renato
Format: eBook
Published: Newark : John Wiley & Sons, Incorporated, 2017.
Online Access:Click for online access
Table of Contents:
  • Cover; Title Page; Copyright; Contents; Preface; List of Abbreviations; Chapter 1 Asymmetric Cyclopropanation; 1.1 Introduction; 1.2 Simmons-Smith Cyclopropanation; 1.2.1 Chiral Substrates; Chiral Allylic Alcohols; Chiral Allylic Amines; Chiral Acetal-Directed Cyclopropanations; Simple Chiral Alkenes; 1.2.2 Chiral Auxiliaries; 1.2.3 Chiral Catalysts; Charette's Ligand; Other Stoichiometric Ligands; Walsh' Procedure; True Catalytic Procedures; 1.3 Transition-Metal-Catalyzed Decomposition of Diazoalkanes.
  • 1.3.1 Intermolecular Cyclopropanation1.3.1.1 Chiral Auxiliaries; Chiral Catalysts: Cobalt; Chiral Catalysts: Copper; Chiral Catalysts: Rhodium; Chiral Catalysts: Ruthenium; Chiral Catalyst: Other Metals; 1.3.2 Intramolecular Cyclopropanation; Chiral Auxiliaries and Chiral Compounds; Chiral Catalysts; 1.3.3 Chiral Stoichiometric Carbenes; 1.4 Michael-Initiated and Other Ring Closures; 1.4.1 Chiral Substrates; 1.4.2 Chiral Auxiliaries; Chiral Michael Acceptors; Chiral Nucleophiles; 1.4.3 Organocatalysis; Ylides.
  • Nitrocyclopropanation1.4.3.3 Halocarbonyl Compounds; 1.4.4 Metal Catalysis; 1.4.5 Other Ring Closures; 1.5 Miscellaneous Reactions; 1.5.1 Rearrangement of Chiral Oxiranes; 1.5.2 Cycloisomerization of 1,n-Enynes; 1.5.3 Denitrogenation of Chiral Pyrazolines; 1.5.4 C-H Insertion; 1.5.5 Addition to Cyclopropenes; 1.5.6 Other Methods; 1.6 Conclusions; References; Chapter 2 Asymmetric Aziridination; 2.1 Introduction; 2.2 Aziridination Based on the Use of Chiral Substrates; 2.2.1 Addition to Alkenes; Aziridination via Nitrene Transfer to Alkenes.
  • Aziridination via Addition-Elimination Processes2.2.1.3 Miscellaneous Reactions; 2.2.2 Addition to Imines; Methylidation of Imines; Aza-Darzens and Analogous Reactions; Addition/Elimination Processes; Miscellaneous Reactions; 2.2.3 Addition to Azirines; 2.2.4 Aziridination via Intramolecular Substitution; From 1,2-Amino Alcohols; From 1,2-Amino Halides; From 1,2-Azido Alcohols; From 1,2-Amino Sulfides and 1,2-Amino Selenides; From Epoxides; 2.2.5 Miscellaneous Reactions.
  • 2.3 Aziridination Based on the Use of Chiral Catalysts2.3.1 Aziridination via Nitrene Transfer to Alkenes; Cu-Catalyzed Aziridination; Rh-Catalyzed Aziridination; Ru-Catalyzed Aziridination; Catalysis by Other Metals; Organocatalyzed Aziridination; 2.3.2 Aziridination via Carbene Transfer to Imines; Carbene Methodology; Sulfur-Ylide-Mediated Aziridination; 2.3.3 Miscellaneous Reactions; 2.3.4 Kinetic Resolutions of Aziridines; 2.4 Conclusions; References; Chapter 3 Asymmetric Epoxidation; 3.1 Introduction.