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|a 1004438796
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|a 9783527679928
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|a QD461.F75 2018
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|a HCDD
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|a Friedrich, JÃœrg.
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|a Metal-Polymer Systems :
|b Interface Design and Chemical Bonding.
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|a Newark :
|b John Wiley & Sons, Incorporated,
|c 2017.
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|a 1 online resource (446 pages)
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|a text
|b txt
|2 rdacontent
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|a computer
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|a online resource
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|a Print version record.
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|a Cover -- Title Page -- Copyright -- Contents -- Preface -- Chapter 1 High-Performance Metal-Polymer Composites: Chemical Bonding, Adhesion, and Interface Design -- 1.1 Introduction -- References -- Chapter 2 Interpretation of Adhesion Phenomena -- Review of Theories -- 2.1 General -- 2.2 Mechanical Interlocking -- 2.2.1 Mechanical Interlocking in a Macroscopic Scale -- 2.2.2 Mechanical Adhesion on a Microscale -- 2.2.3 Mechanical Anchoring on a Molecular Scale -- 2.3 Interdiffusion -- 2.3.1 Diblock Copolymers for Interface-Crossing Adhesion Promotion -- 2.3.2 Interdiffusion and Welding -- 2.3.3 Diffusion of Metals into Polymers -- 2.4 Interphase Formation -- 2.4.1 Polymer-Polymer Blends -- 2.4.2 Nanoparticle Composites -- 2.4.3 Transcrystalline Layers -- 2.4.4 Redox Reactions across the Metal-Polymer Interface -- 2.4.5 Reactions of Transition Metals with Aromatic Polymers -- 2.4.6 Loss in Anisotropic Orientation of Polymers Caused by Pretreatment or by Contact to Metals -- 2.4.7 Weak Boundary Layer -- 2.5 Weak Molecular Interactions (Cohesive Forces) -- 2.5.1 Thermodynamic Adsorption, Wetting Model -- 2.5.2 Contact Angle, Surface Properties, and Adhesion -- 2.5.3 Contact Angle Measurement -- 2.5.4 Advancing and Receding Contact Angles, Contact Angle Hysteresis -- 2.5.5 Real Surfaces -- 2.5.6 Critical Surface Tension -- Zisman Plot -- 2.5.7 Surface Tension Theories -- 2.5.8 Polar and Dispersive Components of Surface Tension -- 2.5.9 Acid-Base Interactions -- 2.5.10 Rheological Model -- 2.5.11 Summary -- 2.6 Electrostatic Attraction -- 2.7 Contaminations, Role of Water, or Humidity -- 2.8 Coupling Agents -- 2.9 Use of Glues (Adhesives) -- 2.10 Hydrophobic Recovery -- References -- Chapter 3 Interactions at Interface -- 3.1 Composites and Laminates -- 3.2 Laminate Processing -- 3.3 Polymers as Substrate or as Coating.
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|a 3.4 Chemical Reactions at Surfaces -- 3.4.1 Chemisorption -- 3.5 Reactions of Metal Atoms with Polyolefins -- 3.6 Reaction of Metal Atoms with O-Functional Groups at Polymer Surfaces -- 3.7 Reactions of Metal Atoms with Amino Groups on Polymer Surfaces -- 3.8 Silane and Siloxane Adhesion-Promoting Agents -- References -- Chapter 4 Chemical Bonds -- 4.1 Bonds in Polymers -- 4.1.1 Covalent chemical bonds chemical bonds in polymers polymers chemical bonds in C-H and C-C Bonds in Polymers -- 4.1.2 C-C Double, Triple, Conjugated, and Aromatic Bonds -- 4.1.3 C-O, C=O, O-C=O, and O=CO-O Bonds in Polymers -- 4.1.4 N-Containing Functional Groups -- 4.1.5 Chemical Bonds in Other Materials -- 4.2 Reactions of Chemical Bonds during Pretreatment -- 4.2.1 Aliphatic Chains -- 4.2.2 Preformed Degradation Products and Preferred Rearrangement Processes -- 4.3 Chemical Bonds at Interface -- 4.3.1 Polymer-Polymer Linking -- 4.3.2 Carbon-Metal Bonds -- 4.3.3 Covalent Bonds between Oxides and Polymers -- 4.3.4 Interface between Polymers and Transition Metals -- References -- Chapter 5 Functional Groups at Polymer Surface and Their Reactions -- 5.1 OH Groups at Surface -- 5.2 Primary Amino Groups at Polymer Surfaces -- 5.3 Carboxylic Groups as Anchor Points for Grafted Molecules -- 5.4 Bromination -- 5.5 Silane Bonds -- 5.6 Click Chemistry -- 5.7 ATRP -- 5.8 Grafting -- 5.8.1 Grafting of Fluorescence Markers onto Functional Groups at Polyolefin Surfaces -- 5.8.2 Covalent Linking of Spacer Bonded Dye Sensors onto Polyolefin Surfaces -- 5.8.3 Covalent Linking of Spacer Bonded Dye Sensors onto Polyolefin Surfaces Supported by a Cucurbituril Jacket -- 5.8.4 Grafting of Polyglycerols onto Polyolefin Surfaces for Introducing Antifouling Property -- 5.8.5 Summary of Complex Structures Covalently Grafted onto Polyolefin Surfaces -- 5.9 Polymers Deposited onto Silicon or Glass.
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|a 5.10 Molecular Entanglement of Macromolecules of Coating and Substrate at Polymer Surfaces (Interpenetrating Network at Interface) -- References -- Chapter 6 Pretreatment of Polyolefin Surfaces for Introducing Functional Groups -- 6.1 Situation at Polyolefin Surfaces -- 6.2 Physical and Chemical Attacks of Polyolefin Surfaces -- 6.3 A Few General Remarks to the Pretreatment of Polyolefins -- 6.4 Introduction of Functional Groups to polyolefin Surfaces -- 6.5 Usual Pretreatment Processes and Their Advantages and Disadvantages -- 6.5.1 Oxygen Plasma Exposure -- 6.5.2 Structural Degradation of Polymer on Exposure to Oxygen Plasma -- 6.5.3 Degradation of Polymers by Exposure to Oxygen Plasma -- 6.5.4 Cross-linking of Polymers by Plasma-Emitted UV Radiation -- 6.6 Surface Oxidation by Atmospheric-Pressure Plasmas (Dielectric Barrier Discharge-DBD, Atmospheric Pressure Glow Discharge-APGD or Corona Discharge, Spark Jet, etc.) -- 6.7 Flame Treatment -- 6.8 Silicoater Process (Pyrosil) -- 6.9 Laser Ablation -- 6.10 UV Irradiation with Excimer Lamps -- 6.11 Ozone -- 6.12 Mechanical Pretreatment -- 6.13 Cryogenic Blasting -- 6.14 Skeletonizing -- 6.15 Roughening for Mechanical Interlocking and Increasing of Surface Area by Plasma and Sputter Etching -- 6.16 Solvent Cleaning -- 6.17 Solvent Welding -- 6.18 Chemical Treatment by Chromic Acid and Chromo-Sulfuric Acid -- 6.19 Chemical Etching and Functionalizing of Fluorine-Containing Polymers -- 6.20 Oxyfluorination -- 6.21 Sulfonation -- 6.22 Sputtering for Film Deposition -- 6.23 Cross-linking as Adhesion Improving Pretreatment (CASING) -- 6.24 Monosort Functionalization and Selective Chemical Reactions -- 6.24.1 Well-Defined Functionalization of Polymer Surfaces by Classic Organic Chemistry.
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|a 6.24.2 Selective Monosort Functionalization of Polymer Surfaces by Oxygen Plasma Exposure and Post-Plasma Chemical Treatment for Producing OH Groups -- References -- Chapter 7 Adhesion-Promoting Polymer Layers -- 7.1 General -- 7.2 Historical Development -- 7.3 Influence of Plasma Wattage on Chemical Structure of Plasma Polymers -- 7.4 Pulsed-Plasma Polymerization -- 7.5 Pressure-Pulsed Plasma -- 7.6 Copolymerization in Pulsed Plasmas -- 7.7 Some Additional Details to the Mechanisms of Plasma Polymerization -- 7.8 Often-Observed Abnormal Side Reactions Occurring in the Plasma Only -- 7.9 Structure of Plasma Polymers -- 7.10 Use of Plasma Polymers as Adhesion-Promoting Layers -- 7.11 Adhesion Promotion of Very Thick Layers -- 7.12 Summary -- References -- Chapter 8 Monosort Functional Groups at Polymer Surfaces -- 8.1 Introduction -- 8.2 Bromination of Polyolefin Surface by Exposure to the Br2 Plasma -- 8.3 Bromoform as Precursor -- 8.4 Deposition of Plasma Polymers Carrying C-Br Groups -- 8.5 Loss in Bromine Groups by Wet-Chemical Processing -- 8.6 Other Halogenations -- 8.6.1 Chlorination -- 8.6.2 Fluorination -- 8.6.3 Iodination -- 8.6.4 Measuring the Electron Temperature in Haloform Plasmas -- 8.6.5 Comparison of Halogenation Processes -- 8.7 C-Br as Anchoring Point for Grafting -- 8.7.1 Changing the C-Br Functionalization into NH2 Functionalization -- 8.7.2 Other Functional Groups -- 8.7.3 Grafting onto C-Br Groups -- 8.8 Underwater Capillary Discharge Plasma or Glow Discharge Electrolysis (GDE) -- 8.9 Conclusions -- References -- Chapter 9 Chemical Grafting onto Monosort Functionalized Polyolefin Surfaces -- 9.1 General Aspects -- 9.2 Grafting of Spacers onto Radicals -- 9.3 Grafting of Spacers and Oligomers by Reaction with C-OH Groups at the Polyolefin Surface -- 9.4 Grafting of Linear Spacers and Oligomers onto C-Br Groups.
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|a 9.5 Introduction of Spacers with Siloxane Cages (POSS) -- 9.6 Grafting via Click Reaction -- 9.7 Influence of Spacers on the Metal-Polymer Adhesion -- 9.8 Summary -- References -- Chapter 10 Conclusions and Outlook to the New Interface Design -- 10.1 Introduction -- 10.2 Physical Effects Produced by Covalent Bonding of Metal to Polymer -- 10.3 Introduction of Functional Groups onto Polyolefin Surfaces Associated with Damaging of Polymer Structure Near Surface -- 10.4 Thermal Expansion Coefficients of Metals and Polymers -- 10.5 Differences between Al-Polyolefin and Polyolefin-Al Laminates -- 10.6 Protection of Covalent Metal-Polymer Bonds along the Interface -- 10.7 Reaction Pays for Grafting Spacer Molecules onto Polyolefin Surfaces -- 10.8 Special Requirements for Metal Deposition Especially Aluminum -- 10.9 Used Ways to Introduce Spacers for Maximum Adhesion -- 10.9.1 Spacer Attachment onto NH2 Groups -- 10.9.2 Spacer Grafting onto OH-Groups at Polymer Surface -- 10.9.3 Spacer Anchoring onto C-Br Groups -- 10.9.4 Silane Attachment -- 10.9.5 Silane Hydrolysis and Subsequent Partial Cross-linking -- 10.9.6 Adhesion Strength Measurements -- 10.9.7 Summary and Conclusions -- References -- Chapter 11 Short Treatise on Analysis Chemical Features -- 11.1 General -- 11.2 Bulk Analysis -- 11.2.1 Infrared Spectroscopy -- 11.2.2 UV-vis spectroscopy -- 11.2.3 NMR Spectroscopy -- 11.2.4 MALDI- and ESI-ToF-MS -- 11.2.5 HPLC and GPC/SEC -- 11.3 Surface Analysis -- 11.3.1 Sampling Depth -- 11.3.2 XPS -- 11.3.3 ToF-SIMS -- 11.3.4 SEIRA and IRRAS -- References -- Index -- EULA.
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|a Chemical bonds.
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|i Print version:
|a Friedrich, JÃœrg.
|t Metal-Polymer Systems : Interface Design and Chemical Bonding.
|d Newark : John Wiley & Sons, Incorporated, ©2017
|z 9783527336777
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|u https://ebookcentral.proquest.com/lib/holycrosscollege-ebooks/detail.action?docID=5047923
|y Click for online access
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