Handbook of Graphene Materials.

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Bibliographic Details
Main Author: Tiwari, Ashutosh
Other Authors: Palys, Barbara
Format: eBook
Language:English
Published: Newark : John Wiley & Sons, Incorporated, 2019.
Subjects:
Online Access:Click for online access
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Table of Contents:
  • Cover
  • Title Page
  • Copyright Page
  • Contents
  • Preface
  • Section 1: Biosensors
  • 1 Graphene-Based Biosensors: Fundamental Concepts, Outline of Utility, and Future Scopes
  • 1.1 Introduction
  • 1.2 Graphene Fabrication
  • 1.3 Fundamental Concepts
  • 1.3.1 Electrical Properties
  • 1.3.1.1 Basic Electrochemistry of Graphene
  • 1.3.1.2 Direct Electrochemistry of Enzymes
  • 1.3.2 Optical Properties
  • 1.4 Outline of Utility
  • 1.4.1 Glucose Biosensor
  • 1.4.2 NADH Biosensor
  • 1.4.3 Hemoglobin Biosensor
  • 1.4.4 Cholesterol Biosensor
  • 1.4.5 Dopamine Biosensor
  • 1.5 Future Scopes and Conclusions
  • References
  • 2 Graphene for Electrochemical Biosensors in Biomedical Applications
  • 2.1 Introduction
  • 2.2 Graphene for Electrochemical Sensing
  • 2.3 Graphene for Biomedical Device
  • 2.4 Graphene for Biological Imaging
  • 2.5 Conclusions
  • References
  • 3 Graphene-Based Biosensors in Agro-Defense: Food Safety and Animal Health Diagnosis
  • 3.1 Introduction to Graphene
  • 3.1.1 Properties of Graphene
  • 3.1.1.1 Electrical Properties
  • 3.1.1.2 Mechanical Strength
  • 3.1.1.3 Optical Properties
  • 3.1.2 Synthesis of Graphene
  • 3.1.2.1 Mechanical Exfoliation
  • 3.1.2.2 Epitaxial Growth on Silicon Carbide
  • 3.1.2.3 Epitaxial Growth on Metal Substrate
  • 3.1.2.4 Graphite Oxide Reduction
  • 3.1.2.5 Growth from Metal-Carbon Melts
  • 3.1.2.6 Unzipping of Nanotubes
  • 3.1.3 Application of Graphene in Sensor Development
  • 3.1.4 Graphene Field-Effect Transistor
  • 3.2 Importance of Biosensors for Agro-Defense
  • 3.3 Graphene-Based Biosensors for Food Safety
  • 3.3.1 Detection of Pesticides
  • 3.3.2 Biosensors for Mycotoxin
  • 3.3.3 Biosensors for Allergens
  • 3.3.4 Biosensors for Bisphenol-A
  • 3.3.5 Biosensors for Microbial Pathogens
  • 3.4 Graphene-Based Biosensors for Animal Safety
  • 3.4.1 Biosensors for Animal Diseases.
  • 3.4.2 Biosensors for Metabolic Disorders
  • 3.4.3 Biosensors for Progesterone
  • 3.4.4 Biosensors for Influenza
  • 3.5 Summary
  • References
  • 4 Trends and Frontiers in Graphene-Based (Bio)sensors for Pesticides Electroanalysis
  • 4.1 Graphene Electrochemical Properties
  • 4.2 Graphene-Based Sensors
  • 4.2.1 Sensors Based on Electrode Modification with Graphene
  • 4.2.2 Sensors Based on Graphene Combined with Other (Nano)materials
  • 4.3 Graphene-Based Biosensors
  • 4.3.1 Enzymatic Biosensors
  • 4.3.1.1 Enzymatic Biosensors Based on Electrode Modification with Graphene
  • 4.3.1.2 Enzymatic Biosensors Based on Graphene Combined with Other (Nano)materials
  • 4.3.2 Graphene-Based Immunosensors
  • 4.4 Concluding Remarks
  • Acknowledgments
  • References
  • 5 Graphene-Based Biosensors: Design, Construction, and Validation. Toward a Nanotechnological Tool for the Rapid in-Field Detection of Food Toxicants and Environmental Pollutants
  • 5.1 Introduction
  • 5.2 Graphene Fabrication
  • 5.3 Graphene Functionalization
  • 5.4 Graphene-Based Biosensors
  • 5.4.1 Bio-Field-Effect Transistors
  • 5.4.2 Impedimetric Biosensors
  • 5.4.3 Surface Plasmon Resonance Biosensors
  • 5.4.4 Fluorescent Biosensors
  • 5.4.5 Electrochemical Biosensors
  • 5.5 Technology Evaluation
  • 5.6 Concluding Remarks
  • References
  • 6 Application of Porous Graphene in Electrochemical Sensors and Biosensors
  • 6.1 Introduction
  • 6.2 Electrochemical Sensors and Biosensors Based on PGR
  • 6.2.1 PGR
  • 6.2.1.1 CVD-Templated PGR
  • 6.2.1.2 PGR Prepared by Template Method
  • 6.2.1.3 Template-Free PGR
  • 6.2.2 Heteroatom-Doped PGR for Electrochemical Sensor
  • 6.2.2.1 Nitrogen-Doped PGR
  • 6.2.2.2 Phosphorus-Doped PGR
  • 6.2.3 Biomolecules/PGR
  • 6.2.3.1 GOD/PGR
  • 6.2.3.2 Horseradish Peroxidase HRP/PGR
  • 6.2.3.3 Antibody/PGR
  • 6.2.4 Metallic Nanomaterials/PGR
  • 6.2.4.1 CVD-Grown PGR.
  • 6.2.4.2 PGR Prepared by Template Method
  • 6.2.4.3 GR Hydrogels or Aerogels
  • 6.2.5 Noble Metal NPs/PGR
  • 6.2.5.1 CVD-Grown PGR
  • 6.2.5.2 PGR Prepared by Template Method
  • 6.2.5.3 PGR Hydrogels or Aerogels
  • 6.2.6 Redox Mediator/PGR
  • 6.3 Outlook and Conclusion
  • References
  • 7 Reduced Graphene Oxide for Biosensing and Electrocatalytic Applications
  • 7.1 Introduction
  • 7.2 Methods of RGO Synthesis
  • 7.2.1 Synthesis of Graphite Oxide
  • 7.2.2 Chemical Reduction of Graphene Oxide
  • 7.2.3 Hydrothermal Reduction
  • 7.2.4 Photoreduction
  • 7.2.5 Electrochemical Reduction
  • 7.3 Characterization of GO and RGO
  • 7.3.1 Chemical Composition: Infrared Spectra and XPS
  • 7.3.2 Structural Aspects: Raman Spectra of GO and RGO
  • 7.4 RGO in Biosensors and Biofuel Cells
  • 7.5 Enzyme-Free Sensors: Composite Materials with RGO and Metal Nanoparticles
  • 7.5.1 Electrochemical Sensors
  • 7.5.2 Pseudoperoxidase Activity-Colorimetric Sensing
  • 7.5.3 Fluorescence Sensors
  • 7.5.4 SERS Sensors
  • 7.6 3D Structures Based on RGO
  • 7.6.1 Synthesis of the 3D RGO
  • 7.6.2 Applications of RGO Hydrogels and Sponges
  • 7.6.2.1 Supercapacitors
  • 7.6.2.2 Drug Delivery
  • 7.6.2.3 Sensing
  • 7.7 Summary and Perspectives
  • References
  • 8 Recent Progress in the Graphene-Based Electrochemical Biosensors Development
  • 8.1 Introduction
  • 8.2 Graphene Forms for Electrochemical Biosensing
  • 8.2.1 Graphene
  • 8.2.1.1 Biomolecules in an Electrode Material
  • 8.2.1.2 Biomolecules as a Target
  • 8.2.1.3 Biomolecules in an Electrode Material and as a Target
  • 8.2.2 Graphene Oxide
  • 8.2.2.1 Biomolecules in an Electrode Material
  • 8.2.2.2 Biomolecules as a Target
  • 8.2.2.3 Biomolecules in an Electrode Material and as a Target
  • 8.2.3 Reduced Graphene Oxide
  • 8.2.3.1 Biomolecules in an Electrode Material
  • 8.2.3.2 Biomolecules as a Target.
  • 8.2.3.3 Biomolecules in an Electrode Material and as a Target
  • 8.2.4 Graphene Quantum Dots
  • 8.2.4.1 Biomolecules in an Electrode Material
  • 8.2.4.2 Biomolecules as a Target
  • 8.2.4.3 Biomolecules in an Electrode Material and as a Target
  • 8.3 Summary
  • Acknowledgments
  • References
  • 9 Electrochemical Biosensors Based on Green Synthesized Graphene and Graphene Nanocomposites
  • 9.1 Introduction
  • 9.2 Enzyme-Based Electrochemical Sensors for the Determination of Glucose Using Green Synthesized Graphene and Graphene Nanocomposites
  • 9.2.1 Glucose Biosensor
  • 9.2.2 Hydrogen Peroxide Biosensor
  • 9.2.3 Phenol Biosensor
  • 9.2.4 Acetylcholinesterase Biosensor
  • 9.2.5 Lipid Biosensor
  • 9.3 Electrochemical Genosensors Using Green Synthesized Graphene and Graphene Nanocomposite
  • 9.3.1 Listeria monocytogenes
  • 9.3.2 Vibrio parahaemolyticus
  • 9.4 Electrochemical Aptasensor Using Green Synthesized Graphene and Graphene Nanocomposite Aptamers
  • 9.4.1 Tumor Markers
  • 9.4.2 Bacteria
  • 9.4.3 Lysozyme
  • 9.5 Electrochemical Immunosensor Using Green Synthesized Graphene and Graphene Nanocomposite
  • 9.5.1 Tumor Marker
  • 9.5.2 Bacteria
  • 9.5.3 Virus
  • 9.5.4 C-Reactive Protein
  • 9.5.5 Cancer Cell
  • 9.6 Lectin-Based Biosensor
  • 9.6.1 Cancer Cell
  • 9.6.2 Glycoprotein
  • 9.7 Conclusion
  • Acknowledgments
  • References
  • 10 Recent Biosensing Applications of Graphene-Based Nanomaterials
  • 10.1 Introduction to Biosensors
  • 10.2 Graphene, Its Variants, and Features for Biosensing Applications
  • 10.3 Recent Most Biosensing Applications of Graphene and Its Variants
  • 10.3.1 Detection of Diseases
  • 10.3.2 Detection of Viruses
  • 10.3.3 Detection of Microbes
  • 10.3.4 Enzymatic Biosensors
  • 10.3.5 Nonenzymatic or Catalytic Sensing
  • 10.3.6 Detection of Toxins/Additives/Pesticides for Food and Environment
  • 10.3.7 Detection of Polyphenols.
  • 10.3.8 Detection of Hormones
  • 10.3.9 Detection of Drugs
  • 10.3.10 Detection of Heavy Metals
  • 10.3.11 Detection of GM Foods
  • 10.3.12 Detection of Glycoproteins
  • 10.3.13 Detection of Cellular Measurements, Viability, Capture, etc.
  • 10.3.14 Heterodyne Sensing
  • 10.3.15 Theranostic Applications: Imaging, Drug Delivery, and Photodynamic Therapy
  • 10.3.16 pH Sensors
  • 10.4 Real-World Applications of Graphene-Based Biosensors
  • 10.5 Conclusions and Future Prospects
  • References
  • 11 Graphene-Based Sensors: Applications in Electrochemical (Bio)sensing
  • Abbreviations
  • 11.1 Introduction
  • 11.1.1 Why Apply Graphene-Based Materials in Electrochemical Sensing Devices?
  • 11.2 Graphene and Graphene-Based Materials: Applications in Electrochemical Sensing and Biosensing
  • 11.2.1 Graphene (G)
  • 11.2.2 Graphene Oxide (GO)
  • 11.2.3 Reduced Graphene Oxide (rGO)
  • 11.2.4 Graphene Quantum Dots (GQDs), Graphene Oxide QDs (GOQDs), and Reduced Graphene Oxide QGs (rGOQDs)
  • 11.3 Final Considerations
  • References
  • 12 Graphene-Based Fiber Optic Label-Free Biosensor
  • 12.1 Introduction
  • 12.2 Recent Advances of Fiber Optic Biosensors
  • 12.3 Novel Configuration of Graphene-Fiber Optic Biosensor
  • 12.3.1 Architecture of GO-LPG and Theory of Mode Coupling
  • 12.3.2 Principle of GO-LPG Biosensing
  • 12.4 Functionalization of GO-LPG Sensor
  • 12.4.1 Fabrication of LPGs
  • 12.4.2 Materials
  • 12.4.3 Surface Modification and GO Deposition
  • 12.4.4 Surface Morphological Characterization
  • 12.5 GO-Based Fiber Optic Immunosensor
  • 12.5.1 Enhanced RI Sensitivity with Thin GO Coating
  • 12.5.2 Biofunctionalization of GO-dLPG
  • 12.5.3 Label-Free Immunosensing of Antibody-Antigen Kinetic Interaction
  • 12.5.4 Reusability of GO-dLPG Immunosensor
  • 12.6 GO-Hemoglobin Biosensor
  • 12.6.1 Transition of Mode Coupling with Thick GO Overlay.